Boot And System Drives Of XP Are Different

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Adept
I am having two HDDs-80GB IDE + 250GB SATA II. I wanted to install my XP on the 250GB HDD i.e where my Vista is installed, n I installed it on G: but Disk Management is showing C: (80GB) as System and G: as Boot. How to make G: as system alongwith boot?
I want to do this becuase I want to install Leo4All on my PC and the installation guide states that it should be installed on a different HDD where no OS is installed previously.
Plz reply me as quickly as prossible.

See this:
http://img65.imageshack.us/img65/9519/problemau0.jpg
 
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